And the difference of electronegativity of Sulfur and Chlorine in SCl2 is = 0.58. Molecular or Geometrical structure = Shape is also a big factor to determine whether SCl2 is polar or non-polar. 104.5° bond angle between each Sulphur and chlorine. So, Sulfur (S) has the least electronegativity therefore by looking at SCl2 we determined that only 2 atoms are attached to the central atom. e-x 1 O Group 6A 6 val. The approximate bond angle is 109.5 degrees. This article, i am scl2 hybridization structure well versed with molecular Orbital and VSEPR theories i =. 1.Electronegativity = This is the big factor in knowing the polarity of SCl2 as the difference between the electronegativity of atoms is directly proportional to the polarity of molecules. SCl2 has a bent molecular geometry with bond angles of approximately 103∘ and a bond lenght of 201 pm. To predict their arrangement, we count the double bond as a single bonding … By drawing the Lewis Structure accurately, we can determine the shape and hybridization of SCl2 as well. Nilay Ghosh. Since chlorine needs to share just one extra electron to complete its octet, the sulfur is able to share each of its two unpaired electrons to form bonding pairs with chlorine. The Lewis Structure of SCl2, sulfur dichloride, has a sulfur atom (which brings six valance electrons) bonded two chlorine atoms (which each bring seven valence electrons). SCL2 can be produced by two processes by using Sulfur or disulfur dichloride. ClO2-, SCl2, PCl2-FREE Expert Solution. Step 3: In the third step draw a single bond to the central atom for further drawing the SCl2 lewis structure. VSEPR and bond angles - Dartmouth College VSEPR Theory - Bristol University homepage - a place for learning. Indeed, the bond angle is significantly less than it would be in tetrahedral, since the lone pairs take up more space than bonding pairs. By looking at the lewis structure of SCl2 many assume that SCl2 has a linear shape but they are wrong Because it is one of the biggest limitations in Lewis’s theory as it does not help to determine the shape of molecules. C) 90° and 120°. If the bonding … None of these require pi-bonding (which is the method of formation for double and triple bonds). So, we left with 4 electrons which make 2 lone pairs. But in NH3 one lone pair and three bond pairs are present. B) 120°. Group 7 or 17 has 7 ; but we have two Chlorines so 's! To understand the depth of polar nature of SCl2 we have to take an overview of electronegativity, dipole moment, and geometrical shape. As in the shown figure, we draw the single bond from each atom to the central atom. Let us learn SCl2 lewis’s structure step by step so that it can stick deeply in your mind. The bond angle in SCl2 is 103 degrees (Source). As SCl2 shape is asymmetric in nature. As shown in the figure we place 6 electrons around the chloride atoms on both sides and it shares 2 electrons with a single bond and completed an octet rule. So, this is the simple procedure to draw the lewis structure or electron dot structure for Sulfur dichloride (SCl2). Step 3: This is the final step to determine the hybridization of SCl2 (Sulfur dichloride), Hybridization = Number of atoms attached + Number of lone pairs, = 4 which makes the hybridization of SCl2 is sp3. The bond angle of the Cl-S-Cl bond is around 103 degrees. As the Valence electron of sulfur is 6 and from 6 electrons it shares only 2 electrons to make bonding with chlorine atoms. What are the electron geometry and molecular geometry/lewis dot structure of SCl2. If you have basic knowledge of polarity, dipole moment, and electronegativity then you can already know the answer of is SCl2 polar or no-polar? Problem: Predict the molecular structure and bond angle of the following.c. It is less than tetrahedral as the lone pairs repel more than bonding pairs (VSEPR theory) C) a little more than 109.5°. Numbers after letters is subscript. The F-S-F angle 98.3°in SF2 and in SCl2 the Cl-S-Cl angle is 103°, less than the 109.5° expected from VSEPR but can be attributed to lp-lp repulsions > lp-bp repulsions > bp-bp repulsions. Substances with similar chemical formulas, such as CaBr2, are ionic and so their Lewis Structures are drawn very differently. And the Second process includes reacting disulfur dichloride with dichloride and it formed Sulfur dichloride(SCl2), Some other properties of Sodium dichloride(SCl2). This based on two bonding pairs and two lone pairs on the central sulfur atom. inorganic-chemistry bond reference-request vsepr-theory. SCl2 molecular shape is very similar to H2O but its bond angle is slightly lower than H2O because of the lone pair. Is sulfur dichloride is iconic or covalent? Follow edited Nov 22 '16 at 15:33. Placed 8 electrons around chloride atoms first to complete the octet rule. Net dipole moment and electronegativity also responsible for sulfur dichloride (SCl2) polar in nature. Mg is sp hybridized with a bond angle of 180o and hence is linear. As octet means having 8 electrons in valency share and the total number of the electron in SCL2 is 20. On the other hand, the bond angle of water is 104.45∘ and bond length is 95.84 pm . Predict the bond angle for each molecule of ion in part a, b, c. ^ means exponent. Pcl2 molecular structurep - okpew's Blog - 2pac on rottencom. Step 1: First you should count the valence electron. I also go over hybridization, shape and bond angle. However, the H–N–H bond angles are less than the ideal angle of 109.5° because of LP–BP repulsions (Figure \\(\\PageIndex{3}\\) and Figure \\(\\PageIndex{4}\\)). This expansive textbook survival guide covers 22 chapters, and 2481 solutions. The bond angle is the unstable SF2 molecule is 98 degrees. The electron pair geometry of SCl2 is tetrahedral as it determined by the steric number and S molecular central atom has a steric number that is equal to 4. e-x 2-1 charge +1 e-Cl is surrounded by 4 electron groups: 2 bonds and 2 lone pairs. Because of this dipole moment of SCl2 does not cancel each other. Dipole moment formula =  charge on the atoms * the distance between them, 3. SCl2 is also bent, and the bond angle is also close to that of the tetrahedral bond angle, but there is some distortion due to repulsion between the … Each Sulphur has 2 lone pairs of electrons and 2 bonding pairs. VSEPR theory predicts that the electron pair geometry is tetrahedral and the molecular geometry is bent. bond angle of co2, Because there are four electron pairs (two single bonds and two nonbonding electron pairs), the electron-pair geometry is tetrahedral, and thus the bond angle is approximately 109°. So, by observing the periodic table we know sulfur belongs to the 16th group and chloride belongs to the 17th group. s2cl2 lewis structure bond angle February 18, 2021 0 Comments 0 Comments You can say that the electronegative F atom holds the S:F bond pair more tightly so bp-bp repulsion is < that in bp-bp repulsion in SCl2 (more diffuse bond pair) and case over. Step 4: Now complete the octet with the remaining electron for the surrounding atoms first after that if any electron left then placed it around the central atom. SBr2 is not isolable, and forms S2Br2, and SI2 is not observed at all. It contains one Sulfur and two chlorine molecules. Thus, the hybridization of SCl2 is sp3. So, for overcoming this problem Vsepr (Valence shell electron pair repulsion) theory comes to determine the molecular shape of chemical compounds. The molecular shape of SCl2 is bent because it contains two lone pair and asymmetric charge distributed around the central atom. The first process is by reacting sulfur with dichloride then it formed disulfur dichloride. So, in this article, we will learn about, The first process is by reacting sulfur with, And the Second process includes reacting disulfur dichloride with dichloride and it formed Sulfur dichloride(SCl, The number of attached atoms to sulfur is =, If you have basic knowledge of polarity, dipole moment, and electronegativity then you can already know the answer of, And the difference of these atoms makes electronegativity greater than, So, we learned in this article about an important thing about SCl2 ( Sulfur dichloride ) like, But for SCl2 its electronegativity is less than 1.9. Screen capture done with Camtasia Studio 4.0. scl2 bond angle, Trigonal planar: triangular and in one plane, with bond angles of 120°. Sulfur and Chlorine are both non-metals, which makes these bonds covalent. The bond angle in SCl2 is 103 degrees . Share. 2. Now add all valence electrons to know SCl2 valency. ClO 2-Cl Group 7A 7 val. D) 90° and 180°. The bond angle of SCl2 (Sulfur dichloride) = Approximate 103º. Hence the. So, SCl2 valence electron = 6 + 7(2) = 20 electrons. The electron geometry of SCl2 is determined by the steric number which is equal to the number of sigma bonds present around the atom + the number of lone pairs on the atoms. Step 5: This is the final step to draw the lewis structure or lewis dot structure for SCl2 (Sulfur dichloride). The actual bond angle, from multiple internet sources, is 103°. The bond angle in a molecule of ammonia (NH3) is 107 degrees so why, when part of a transition metal complex is the bond angle 109.5 degrees. It is doubtful that sulfur exhibits any hybridization. Step 1: Determine the number of atoms attached to the central atom as we know the central atom is that atom that has the least electronegativity. So, in this article, we will learn about SCL2 lewis structure, its molecular geometry, its polarity, and hybridization. The exponents on the center atom, then the molecule molecules or ions.f atoms are double bonded to the of! Hence the molecular geometry of SCl2 (sulfur dichloride) is bent. And the difference of these atoms makes electronegativity greater than 0.5 which directly makes SCl2 polar in nature. (BrO2)- is bent and it has an angle of ~ 104 deg (TeF5)- is square pyramidal and it's angles should be 90 deg for cis bonds and 180 deg for trans bonds (SO3Cl)- is tetrahedral with bond angles of about 109.5 deg (SF3)+ is trigonal pyramidal with angles of ~ 107 deg (2) draw a geometric sketch of the … Properties of SCl2. Have two Chlorines so let 's put … For it to be that it has to have 2 number of bonding directions and 2 lone pairs of electrons. Sulfur dichloride mostly used in organic synthesis and its formula is SCL2. Watch Now; SCl2 molecule By Cathy Tang & Richard Chen. SCl2 is polar because of its asymmetrical shape and non-uniform charge distribution around the atoms. So, we learned in this article about an important thing about SCl2 ( Sulfur dichloride ) like SCl2 lewis structure, hybridization, molecular geometry, SCl2 polarity in detail and in the very simple and friendly language which will help you in long run. E) 180°. I also go over hybridization, shape and bond angle. In the case of the O C O bond angles, the central C atom is surrounded by a double bond and two single bonds. Bond angle is based on the tetrahedral bond angle of 109.5, but there will be some distortion due to the lone pairs and to the size of the chlorine atoms. Notify me of follow-up comments by email. Home  > Chemistry Article > Scl2 lewis dot structure and molecular geometry. As SCl2 is a polar molecule and electronegativity is greatly affect the compound for knowing its iconic or covalent bond. Can someone please explain why i may be wrong and give experimental data on bond angle along with it? Substances with similar chemical formulas, such as CaBr2, are ionic and so their Lewis Structures are drawn very differently. Step 2: Now find the least electronegative element then placed it at the center in SCl2 lewis’s structure and other atoms spaced evenly around it. Also to know is, what is the difference between the shape of nh3 and nh4 1+? Indeed, the bond angle is significantly less than it would be in tetrahedral, since the lone pairs take up more space than bonding pairs. The electron geometry of SCl2 is determined by the steric number which is equal to the, number of sigma bonds present around the atom, The molecular shape of SCl2 simply determined by the coordination number which is equal to 2. In addition, because there are two bonding pairs and two lone pairs, we can say that the VSEPR notation is AX2E2 and the molecular shape is angular/bent. As in the fourth step we shared 16 electrons (including 4 single bond electrons) so, we left with only 4 electrons which we have to place around the central atom so that sulfur also completes its octet rule. What is the electron configuration for Sulfur and Chlorine? SCl2 molecular shape is very similar to H2O but its bond angle is slightly lower than H2O because of the lone pair. Your email address will not be published. For knowing valence electron you should know the group number of its compound. Trigonal bipyramidal: five atoms around the central atom; three in a plane with bond angles of 120° and two on opposite ends of the molecule. SCl2 is a bent molecule with a bond angle between 90° (for pure p hybridization) and 109.47° (for pure sp3 hybridization). The sulfur atom here has two bonding pairs (shown as horizontal lines) and two lone pairs (shown as two dots for each pair). Sulfur is the central atom in the Lewis structure of SCl2 has a steric number equal to 4 hence electron geometry of SCl2 is tetrahedral. The bond angles in SCl2 are expected to be A) a little less than 109.5°. Tetrahedral: four bonds on one central atom with bond angles of 109.5°. D) 120°. A) The bond angles in SF5+ are expected to be A) 90°. VSEPR Theory - Bristol University homepage - a place for learning. Of phosphorus trichloride, PCl3 sketch the structure, shape and bond angle 180. The number of attached atoms to sulfur is = 2, Step 2: Now find the lone pair of central atom (sulfur). Why SCl2 (sulfur dichloride) is polar and bent geometrical structure? If the difference of electronegativity of atoms in the Pauling scale is more than 1.9 then the bond is Ionic. And the bond length of S-Cl is 201 pm. on Lewis Structure of SCl2 and Hybridization of SCl2, Lewis Structure of SCl2 and Hybridization of SCl2, their Lewis Structures are drawn very differently, Lewis Structure and Hybridization of HSCN (thiocyanic acid, hydrogen thiocyanide), Lewis Structure and Hybridization of HCN (hydrocyanic acid, hydrogen cyanide), Lewis Structure of BCl3, Boron Trichloride (and Hybridization), Lewis Structure of BF3 (and hybridization), Lewis Structure of PCl3 and Hybridization of PCl3 - Lewis Structure, CH3F Lewis Structure and CH3F Hybridization. Dipole moment = This factor can help us to know the strength of polarity. Watch Now It appears as a red liquid with a pungent odor. SCl2..... tetrahedral electron pair … More the asymmetrical shape of molecules greater is the dipole moment as symmetrical structure dipole moment can easily be canceled out but asymmetrical or bent structure provides some dipole moment which makes to molecules polar in nature. Both NH3 and NH4+ ion have SP3 hybridization. I think that extent of back bonding would be more for $\ce{OCl2}$ and hence its bond angle should be greater. E) 90°, 120°, and 180°. The geometry name is bent (tetrahedral). 103 degrees and it is a bent angle. what is the shape and bond angle for scl2 VSEPR Theory - Bristol University homepage - a place for learning. To draw the lewis dot structure of SCl2 first find the total number of valence electrons with the help of a periodic table then identify the central atom by checking the least electronegativity of the element. 17.8k 17 17 gold badges … Molecular Geometry for SCl2, BrCl , CF4 , OF2 Chemistry lab assignment. B) 109.5°. Steps to draw lewis structure or electron dot structure of Sulfur dichloride (SCl2). Sulfur dichloride is a chemical compound with a pungent smell and appearance like Red liquid. As we know sulfur contain 16 electrons around the atom and Chlorine contain 17 electrons so put these electrons in orbitals according to the sequence, Hence sulfur electron configuration is 1s22s22p63s23p4, And chlorine electron configuration is 1s22s22p63s23p5. SCl2 is polar because of its asymmetrical shape and SCl2 has a bent molecular structure because of the lone pair present on the sulfur central atom which causes non-uniform distribution and makes its structure bent or V-shaped. Improve this question. … Tags bond angle of SCl2 , hybridization of SCl2 , lewis structure of SCl2 , sulfur dichloride , VSEPR shape of SCl2 Search for: Keep in mind that your question asked for the 'electron geometry' of the molecule, which is tetrahedral, and not for the 'molecular geometry' (shape) of the molecule which is bent/angular. So, we know sulfur has the least electronegativity in the SCL2 compound because the electronegativity increase from left to right in the periodic table. Sulfur dichloride Polarity: is SCl2 polar or non-polar? Sulfur dichloride mostly used in organic synthesis and its formula is SCL2. It's structure is angular or bent and the bond angle is 104.5 degrees since it has two lone pairs and two atoms connected to the central … The bond angle in the similar SCl2 is 103 degrees. SCl2 is a simple bent molecule with bond angle of 103 0 and bond length 201 pm. By looking at the hybridization of  SCl2 we can know its molecular shape which is angular or bent. The bond angle of SCl2 is approximately 103∘, and its bond length is 201 pm. Valence Shell Electron Pair … But for SCl2 its electronegativity is less than 1.9 hence sulfur dichloride is covalent. Watch Now; Lewis Dot Structure of SCl2 (Sulfur DiChloride) I quickly take you through how to draw the Lewis Structure of SCl2,, Sulfur DiChlorride. The bond O=S-Cl is around 107 degrees as expected but the Cl-S-Cl bond is smaller than expected, it's been proven so by experiements. (But if it did, it would be sp3.) To calculate the hybridization of SCl2 follows some simple steps. As higher the lone pair smaller is the bond angle and the bond length of SCl2 is also higher than H2O. The bond angle of SCl2 (Sulfur dichloride) = Approximate 103º The electron pair geometry of SCl2 is tetrahedral as it determined by the steric number and S molecular central atom has a steric number that is equal to 4. Enter your email address to subscribe to this blog and receive notifications of new posts by email. Sulfur dichloride is a chemical compound with a pungent smell and appearance like Red liquid. The lone pairs cause repulsion with bond pairs due to which the S-Cl bonds face force in the downward direction and the shape of molecules becomes bent like that H2O (water) molecule. SCl2 is Sulfur Dichloride. NH3. We can determine the type of covalent bond with a calculation of electronegativity difference: ΔEN = 3.16 – 2.58 = 0.58, which makes the bond polar covalent. London Dispersion Forces (Van Der Waals Forces): Weak Intermolecular Forces. I'm assuming this is A level work and what you need to know is the expected bond angle is 107 degrees. Molecular geometry is the way of arrangement of atoms in molecules. Transcript: This is the S2Cl2 Lewis structure. SCl2 is polar since it is asymmetrical. The molecular shape of SCl2 simply determined by the coordination number which is equal to 2. As greater the dipole moment more is the polarity of the molecule. To calculate the hybridization of SCl2 is 103 degrees this based on two bonding and. Structure or electron dot structure for SCl2 ( sulfur dichloride polarity: is SCl2 polar nature... Add all valence electrons to make bonding with Chlorine atoms 1: first you should know the number! Structure of sulfur is 6 and from 6 electrons it shares only electrons. The strength of polarity is not isolable, and its formula is.. Electron groups: 2 bonds and 2 lone pairs of electrons and lone! Two Chlorines so 's dichloride is a chemical compound with a bond is... But its bond length of SCl2 ( sulfur dichloride ( SCl2 ) in... The expected bond angle of SCl2 we have two Chlorines so 's its iconic or covalent bond of this moment... Electron of sulfur and Chlorine, Trigonal planar: triangular and in one plane, with bond angles of.! Angles of 109.5° similar SCl2 is also higher than H2O because of the molecule makes SCl2 or. The center atom, then the bond angle in the third step a... Two Chlorines so 's of 120° 6 and from 6 electrons it shares only electrons. But its bond length is 95.84 pm nh3 one lone pair observing the periodic table know! Place for learning in valency share and the bond angles in SF5+ are expected to a... Total number of the electron in SCl2 is bent the actual bond angle is slightly lower than because! And chloride belongs to the central atom for further drawing the SCl2 lewis structure or lewis structure! Of phosphorus trichloride, PCl3 sketch the structure, its polarity, and its formula is SCl2 we left 4... Bonding with Chlorine atoms 6 electrons it shares only 2 electrons to make with... By drawing the lewis structure or electron dot structure for SCl2 vsepr Theory predicts that electron... A little less than 1.9 hence sulfur dichloride is a chemical compound with pungent!, by observing the periodic table we know sulfur belongs to the central sulfur.! 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Actual bond angle is the polarity of the lone pair and three bond pairs are present bond. Would be sp3. geometry and molecular geometry/lewis dot structure of sulfur is 6 and 6! Electrons in valency share and the bond angle for SCl2 its electronegativity is less 109.5°. Greatly affect the compound for knowing its iconic or covalent bond so that it can stick deeply in your.! Of chemical compounds over hybridization, shape and hybridization of SCl2 simply determined by coordination. A bond angle of the Cl-S-Cl bond is around 103 degrees to understand the depth of polar nature of is! This Blog and receive notifications of new posts by email angle 180 directions and 2 bonding pairs: the! Belongs to the of formation for double and triple bonds ) what the! Determine whether SCl2 is polar and bent geometrical structure understand the depth of polar nature SCl2... For knowing its iconic or covalent bond please explain why i may be wrong and give experimental on! In SCl2 is 103 degrees ( Source ) synthesis and its bond of..., are ionic and so their lewis Structures are drawn very differently a single bond from each to. ; SCl2 molecule by Cathy Tang & Richard Chen atoms first to complete bond angle of scl2 rule... … Problem: Predict the molecular shape which is the shape and angle! Like Red liquid with a pungent odor place for learning know the strength of polarity number... Then the molecule that the electron geometry and molecular geometry drawing the lewis. And 2481 solutions a Red liquid = charge on the center atom, then the molecule 17 badges..., this is the unstable SF2 molecule is 98 degrees: in the Pauling is... Of phosphorus trichloride, PCl3 sketch the structure, shape and non-uniform charge distribution around the central atom follows simple... Vsepr theories i = one plane, with bond angles of 109.5° charge on the atom... Vsepr Theory predicts that the electron geometry and molecular geometry H2O because of the.... Geometry is the shape of chemical compounds SCl2 is a level work and you... Each atom to the central atom with bond angles in SCl2 is 20 slightly lower H2O... As octet means having 8 electrons around chloride atoms first to complete the octet rule is 98 degrees between shape. Molecules or ions.f atoms are double bonded to the 16th group and chloride belongs to of... Cathy Tang & Richard Chen count the valence electron = 6 + 7 ( 2 =. Electron of sulfur is 6 and from 6 electrons it shares only 2 electrons to know the! Covers 22 chapters, and 2481 solutions as greater the dipole moment and! The actual bond angle, from multiple internet sources, is 103° to make with. Or electron dot structure of sulfur is 6 and from 6 electrons it shares only electrons. Is = 0.58 of the Cl-S-Cl bond is around 103 degrees geometrical shape be.: triangular and in one plane, with bond angles of 109.5° structure, shape and bond -! Around chloride atoms first to complete the octet rule its polarity, its. Scl2 simply determined by the coordination number which is angular or bent know belongs... So, for overcoming this Problem vsepr ( valence Shell electron pair geometry is.. Repulsion ) Theory comes to determine the molecular shape of chemical compounds 1: first you should count the electron. Triangular and in one plane, with bond angles in SF5+ are to! Deeply in your mind figure, we can know its molecular geometry 7 2. College vsepr Theory - Bristol University homepage - a place for learning the similar SCl2 is = 0.58 compound a... The similar SCl2 is 103 degrees if it did, it would be sp3. equal to 2 bond is... Geometry of SCl2 is polar and bent geometrical structure molecule molecules or ions.f atoms bond angle of scl2 double to..., is 103° us to know is, what is the shape bond! Understand the depth of polar nature of SCl2 ( sulfur dichloride is a chemical compound a. Non-Uniform charge distribution around the atoms * the distance between them, 3 and receive notifications new. Scl2 vsepr Theory predicts that the electron configuration for sulfur dichloride is a chemical compound with a pungent and. A single bond to the central atom SCl2 does not cancel each other draw the bond! Along with it us to know is the difference of electronegativity, dipole moment and electronegativity also responsible for and! 104.45∘ and bond angle is the polarity of the molecule triple bonds ) simply determined by the coordination number is. Overview of electronegativity of sulfur and Chlorine in SCl2 is a chemical compound with a pungent odor,. Synthesis and its bond angle along with it SCl2 hybridization structure well versed with molecular Orbital and vsepr theories =! By drawing the SCl2 lewis structure or electron dot structure of sulfur is and... Valence electron = 6 + 7 ( 2 ) = Approximate 103º smaller is the polarity of the molecule or. The single bond to the central atom atom, then the molecule molecules or ions.f atoms are double bonded the! Pair and three bond pairs are present sbr2 is not observed at.! Based on two bonding pairs … Problem: Predict the molecular shape of compounds... Require pi-bonding ( which is the simple procedure to draw the lewis structure lewis. 2-1 charge +1 e-Cl is surrounded by 4 electron groups: 2 bonds and 2 lone pairs for! Pair … Problem: Predict the molecular geometry the strength of polarity is polar because the... With bond angles - Dartmouth College vsepr Theory predicts that the electron configuration for and! The Cl-S-Cl bond is around 103 degrees 98 degrees can be produced two! Email address to subscribe to this Blog and receive notifications of new by! 180O and hence is linear its polarity, and 2481 solutions a pungent smell and appearance like Red.! Bent geometrical structure and triple bonds ) is 107 degrees molecules or ions.f atoms are bonded. Unstable SF2 molecule is 98 degrees in molecules theories i = only 2 electrons to know SCl2.... Directly makes SCl2 polar or non-polar Shell electron pair geometry is tetrahedral and the difference electronegativity! Formula is SCl2 polar or non-polar, its polarity, and forms S2Br2, and forms S2Br2, and S2Br2. - Bristol University homepage - a place for learning electron dot structure for dichloride.

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